The Renaissance of Bridged Triarylphosphines: Towards Organophosphorus Molecular Bowls
نویسندگان
چکیده
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A molecular mechanics approach to mapping the conformational space of diaryl and triarylphosphines.
A molecular mechanics force field has been developed which accurately reproduces experimental solid state structures and conformer interconversion barriers for a series of sterically congested diaryl and triaryl phosphines and some of their chalcogenide and Cr(CO)5 derivatives.
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 2019
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.190601